Monday, January 16, 2017

Estimating the leakage of air into a closed bedroom

Estimating the rate of leakage of air into a closed room

This entire exercise is connected with my air purifier which is located in my bedroom and which is turned on after we go to sleep. Unfortunately, despite the fact that all the windows and doors are closed, air from outside the bedroom does get in. I wanted to estimate the rate at which that happens.
I have a digital thermometer-cum-hygrometer. If I measure both T ( degrees Celsius) and relative humidity RH (in %) at night when I go to sleep, and again in the morning, when I wake up, I can estimate the leak rate. The logic is that the temperature will dip towards the morning, and the RH may also change - but the absolute humidity (AH) will remain the same. Unless, there is an inleak of air. So the percentage change in the AH and the volume of the room can give an estimate of the average leak rate (knowing the time beween the two measurements).
Note: the AH is related to the RH & T by the Antoine equation. (I have assumed the values are correct without getting into whether this set of values is the most reliable set.)
I put this to my colleague Haldar and he did not disagree with the above argument but pointed out that if I was sleeping in the room, then the amount of water vapour contributed by exhalation and perspiration would change the AH. I did the calculations and I do not think it makes a large difference - at least in winter! (which is what it is now) - and I also checked it in an unoccupied guest bedroom, and the results are similar. However, the idea of measuring the leakage rate in this way has limited utility - as is explained in detail below...

The bedroom doors (and windows) are closed at night and so the difference in absolute humidity (AH) between night & morning should give the leak rate:
Leakage rate:
Time
Temp (°C)
RH (%)
AH
22:45
20.0
74
12.957
06:30
18.9
76
12.46
06:30
18.8
75
12.18

The AH is calculated from T and RH by the Antoine equation:

Log10 (P) = 8.07131 – [1730.63/(233.426 +T)]

Where p is in Torr, and T is in °C.
In the morning, average AH = 12.32
Percent change: (12.957-12.32)/12.957 = 4.9 %       - over 7hrs 45 mins.
Percent change per hr: 0.0063 /hr.
Total volume of room: 11.25 x 15 x 9 = 1519  ft3 = 42.3 m3
Total volume leak rate per hr: 0.27 m3/hr = 4.5 L/min.
However, a small reality check: the AH in the room went down from 22:45 to 06:30 – but that can only if the AH outside the room went down in this time period.
This did happen, as can be seen from this data from Greater Kailash-I from www.bluebus.com:
Time
Temp (°C)
RH (%)
AH
21:30
14.9
90
11.66
07:15
10.3
98
9.18

That is, AH outside decreased by about 21%.
Next day:
Time
Temp (°C)
RH (%)
AH
23:00       8-12-16
19.4
76%
12.82
07:00      9-12-16
18.8
76%
12.35

Percent change: (12.82-12.35)/12.82 = 3.7 %       - over 8 hrs
Percent change per hr: 0.0046 /hr.
Total volume of room: 11.25 x 15 x 9 = 1519  ft3 = 42.3 m3
Total volume leak rate per hr: 0.20 m3/hr = 3.3 L/min.
Time
Temp (°C)
RH (%)
AH
23:30 9-12-16
19.4
76
12.82
06:30 10-12-16
18.4
77
12.20
07:45   10-12-16
18.2
77
12.05

Percent change: (12.82-12.2)/12.82 = 4.8%       - over 7 hrs
Percent change per hr: 0.0069 /hr.
Total volume of room: 11.25 x 15 x 9 = 1519  ft3 = 42.3 m3
Total volume leak rate per hr: 0.29 m3/hr = 4.9 L/min.
Change in 1.25 hrs: 1.2% i.e. 0.0098 /hr i.e. 7 L/min

Time
Temp (°C)
RH (%)
AH
23:00       10-12-16
18.3
77%
12.125
07:15      11-12-16
16.6
81%
11.453

Percent change: (12.125-11.453)/12.125 = 5.54%       - over 8.25 hrs
Percent change per hr: 0.0067 /hr.
Total volume of room: 11.25 x 15 x 9 = 1519  ft3 = 42.3 m3
Total volume leak rate per hr: 0.284 m3/hr = 4.74 L/min.

Readings for 8th & 9th Jan.17:
a a)      Guest bedroom: empty
Time
Temp (°C)
RH (%)
AH
21:30       8-1-17
17.9
74%
11.363
08:00     9-1-17
16.9
74%
10.665

AH decreases by: 6.14%.
b b)      Main bedroom: 1 sleeper
Time
Temp (°C)
RH (%)
AH
21:30       8-1-17
17.7
80%
12.13
08:00     9-1-17
17.1
79%
11.531



AH decreases by: 4.94%.
c c)       Outside temperatures:
Time
Temp (°C)
RH (%)
AH
21:00       8-1-17
13.8
90%
10.62
08:00     9-1-17
10.3
96%
8.99


AH decreases by: 15.35%.
The AH decreases by a larger percentage in the unoccupied room than in the occupied room – and by the largest percentage in the outside of the house.
Reading on 10th Jan17:
a d)      Main bedroom: 2 sleepers
Time
Temp (°C)
RH (%)
AH
21:30       9-1-17
16.1
71%
9.724
08:00     10-1-17
14.9
73%
9.255



AH decreases by: 4.82%.
b e)      Outside temperatures:
Time
Temp (°C)
RH (%)
AH
21:00       9-1-17
11.0
65%
6.38
08:00     10-1-17
5.8
82%
5.648


AH decreases by: 11.47%.

Breathing contribution:
inhaled water vapour: 4.5 ml per breath (total 500 ml of air per breath).
exhaled water vapor: 31 ml per breath. (total volume exhaled 500 ml per breath).
Total: about 17,000 breaths per day.
Assume 15 breaths per minute, and 10.5 hrs is 630 mins. Total water vapour exhaled:
(0.0265)(630) = 16.7 Litres.
Assuming a 27,000 Litre room, the percentage change in AH due to one sleeper is: 16.7/27000 = 0.062%.
Three sites below add to the confusion – but they are all smaller than what is calculated above:
1)
For the average 70 kg man, it has been measured to be 400 ml due to respiration and 400 ml due to perspiration per 24 hour period of time.
The quora site suggests that an equal amount is lost due to breathing and perspiration.
Note: the quora value for breathing is much smaller than the one calculated above, which is of the order of 38 litres per day!
2)
The average human exhales 0.35 liters of water each day. 
Every day, we breathe in about 14000L of air. Assuming that the humidity of exhaled air is 100% and inhaled air is 20%, and using the carrying capacity of 1kg of air to be 20g of water vapour, we can calculate how much water is lost simply by breathing. This estimate gives 400ml of water lost per day too.
3)
During physical exercise amount of exhaled H2O is linear, but not proportional to heart rate. And so at the heart rate of 140 bpm amount of exhaled water is approximately four times higher than during the rest and equals about 60-70 ml/h. 
The site below gives a formula and analysis that is most credible, but the difference with the earlier estimate (of mb-soft i.e. 31 ml per 500 ml) is 43%:

According to this blog, the air exhaled by a human is at 35 °C and 95% RH.

The partial pressure is calculated from:

P = RH [510.8 exp(17.2694T/(T + 238.3))]

Where T is in °C and p is in Pa.
Plugging in this gives a partial pressure Pw = 4430 Pa
This gives a value of 0.0437, or about 4.4%.
For comparison: the value 31.5/500 = 0.063, or 6.3%.
The agreement is not good (43% off!) – but at least the order of magnitude is right!
Sweating contribution:
Chemistry of the Textiles Industry
edited by C. Carr (1995) p.236
“Sweat rate is 15-30 ml/hr when sleeping in comfort zone temperatures.”
The quora.com site estimates 400 ml/day for a 70 kg man i.e. 17 ml/hr on average, which is within the range of the above values.

LSB error:
However, the problem with the measurements above is the least significant bit (LSB) in the digital display of the meter that I have. The humidity is accurate to 1% and the temperature to 0.1 °C.
Suppose one takes the worst case (error in both RH and T to minimize the difference in AH), on the measurements above for the guest bedroom a) above:
f)
Time
Temp (°C)
RH (%)
AH
21:30       8-1-17
17.8
73%
11.363
08:00     9-1-17
17.0
75%
10.878

In this case, the AH decreases by 2.33% - as compared with 6.14% above! That means that unless the measurements are done with significantly better accuracies the estimated inleak rate could be off by a factor of 2-3X!

Further, one can only use this idea on two measurements done overnight, to get the maximum difference in AH. Also, to avoid door opening which would happen many times in the day!


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